Ordered bulk heterostructure PV cells are more difficult to fabricate than disordered blends, but there are several good reasons to do so. First, the dimensions of both phases can be controlled to ensure that every spot in a film is within an exciton diffusion length of an interface between the two semiconductors. Second, there are no dead ends in the structure. After excitons are dissociated by electron transfer, the electrons and holes have straight pathways to the electrodes. This geometry ensures that the carriers escape the device as quickly as possible, which minimizes recombination. Third, in an ordered structure it is possible to align conjugated polymer chains, which increases the mobility of their charge carriers. Another advantage, which is particularly important during the current stage of organic photovoltaic cell research, is that ordered structures are much easier to model and understand.
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Written by OPV Team ( )
Edited by Kwangwoo Cho ( 2019.11.05 )